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Q.

A quantity of 4.0 moles of an ideal gas at 20°C expands isothermally against a Constant pressure of 2.0 atm from 1.0 L to 10.0 L. If entropy change of system is

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a

10.4

b

18.4

c

19.4

d

15.4

answer is B.

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Detailed Solution

  •  As volume increases, entropy values also increases because disorders increases.
  •  The expression for entropy change with respect to volume is

                        ΔS=2.303nRlogV2/V1;

 by substituting all values, R=2,n=4,V1=1V2=10

 ΔS=2.303×4×2×log10/1;   (log10=1)

 ΔS=2.303×8=18.424

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