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Q.

A reactant ‘A’ decomposes to produce two different products simultaneously, but at  different rate as shown below:
  CE2k2AE1k1B
The order of reaction is unity for both reactions and their respective rate constants  k1  and  k2  are 1.2×102  and 3×102 per second, respectively. Calculate activation energy (in  kJ/mol) for the overall reaction if the activation energy for individual steps E1 and  E2 are  180 and 200 kJ/mol respectively

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answer is 194.

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Detailed Solution

Ans: 194.27 to 194.29

Sol:  E=E1K1+E2K2K1+K2=194.28  kJ/mol.

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A reactant ‘A’ decomposes to produce two different products simultaneously, but at  different rate as shown below:  C←E2k2 A→E1k1BThe order of reaction is unity for both reactions and their respective rate constants  k1  and  k2  are 1.2×10−2  and 3×10−2 per second, respectively. Calculate activation energy (in  kJ/mol) for the overall reaction if the activation energy for individual steps E1 and  E2 are  180 and 200 kJ/mol respectively