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Q.

A reaction : 2A(g)+3B(g)C(g) obeys the following rate law, Rate of reaction =[A]3[B]2.

Select the incorrect options.

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a

The reaction will occur in a single step.

b

If concentration of 'A' and 'B' both are doubled then rate will increase to double the original value.

c

If 'B' is taken in very large amount as compared to 'A' then half life of the reaction will be inversely dependent on cube of its initial concentration.

d

If both 'A' and 'B' are taken in equal concentration then half life will be dependent on their concentration.

answer is A, C.

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Detailed Solution

(a) Reaction is not elementary

(b) New rate =23×22r=2r

(c) lf[B] Is very large, r=k[A]3;t1/2a13 or a2

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