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Q.

A reaction follows first-order kinetics with t₁/₂= 10 min. Find rate constant.

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Detailed Solution

First-order rate constant with t1/2=10 mint_{1/2}=10\ \text{min}
Answer: k=ln2t1/2=0.69310=0.0693 min11.16×103 s1k=\dfrac{\ln2}{t_{1/2}}=\dfrac{0.693}{10}=0.0693\ \text{min}^{-1}\approx1.16\times10^{-3}\ \text{s}^{-1}.
Method: First-order kinetics halves concentration every half-life independent of initial amount. Convert to desired time units by dividing by 60. The integrated law ln[A]0[A]=kt\ln\frac{[A]_0}{[A]}=kt is consistent with this kk. If asked for 90% decay time, use t0.9=ln10/kt_{0.9}=\ln10/k.

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