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Q.

A reaction follows the rate law, R=K[A]m[B]n. From the following information, calculate the value of m and n

 [Al[B]t1/2
12×103M4M20 min
24×103M4M40 min
32×103M8M20min

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a

m = 0, n = 0

b

m = 1, n = l

c

m = 1, n = 0

d

m = 0, n = 1

answer is B.

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Detailed Solution

t1=62π10

20=k=k2×103kn[4]h

40=k=k4×103h[4]n

2=4×1032×103n3  ,  n=0

2=(2)m = m=1

m=1, n=0

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