Q.

A reaction has both H and S negative. The rate of reaction

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a

Cannot be predicted for change in temperature

b

Increases with increase of temperature

c

Remains unaffected by change of temperature

d

Increases with decrease of temperature

answer is A.

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Detailed Solution

G=H-TS

H=-Ve andS=-Ve

At higher temperature magnitude of TS>H ; G=+ve and reaction is non-spontaneous

At low temperature magnitude of TS<H ; G=-ve and reaction is spontaneous

Rate of reaction increases always with increase in temperature

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