A reaction is catalysed by $H^{+}$ ion, and In the rate law the dependence of rate is of first order with respect to the concentration of $H^{+}$ ions, in presence of HA rate constant is $2 \times 10^{- 3} \min^{- 1}$ and in presence of HB rate constant is $1 \times 10^{- 3} \min^{- 1}$ $HA$ and $HB$ have relative strength as :

see full answer

Talk to JEE/NEET 2025 Toppers - Learn What Actually Works!

Real Strategies. Real People. Real Success Stories - Just 1 call away

An Intiative by Sri Chaitanya

0.001

0.5

0.002

answer is D.

(Unlock A.I Detailed Solution for FREE)

Ready to Test Your Skills?

Check your Performance Today with our Free Mock Test used by Toppers!

Take Free Test

Detailed Solution

The ratio of rate constants,

$\frac{k_{1}}{k_{2}} = \frac{{[H^{+}]}_{HA}}{{[H^{+}]}_{HB}} \frac{k_{1}}{k_{2}} = \frac{2 \times 10^{- 9}}{1 \times 10^{- 3}} \frac{k_{1}}{k_{2}} = 2$

Watch 3-min video & get full concept clarity

Result Producing online coaching for JEE/NEET of south India

Largest All India Test Series for JEE/NEET

Best Online Course for IIT JEE

Best Online Course for NEET

Best Online Course for CBSE

Best Courses for You

JEE

NEET

Foundation JEE

Foundation NEET

CBSE

Get Expert Academic Guidance – Connect with a Counselor Today!