Q.

A reaction occurs spontaneously if 

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a

TΔS>ΔH and ΔH is +ve and ΔS is ve

b

TΔS<ΔH and Both ΔH and ΔS are tue 

c

TΔS>ΔH and both ΔH and ΔS are tue 

d

TΔS=ΔH and both ΔH and ΔS are +ve

answer is B.

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Detailed Solution

For spontaneous reaction  G should be negative

ΔG=ΔHTΔS=(+ve)T(+ve)

If TΔS>ΔH then G will be negative and reaction will  be spontaneous at high temperature. 
 

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A reaction occurs spontaneously if