Q.

A reaction occurs spontaneously if 

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a

TΔS>ΔHand  ΔHis+veΔS  isve

b

TΔS>ΔHand  both  ΔHandΔS  are+ve

c

TΔS<ΔHandboth  ΔHandΔS  are+ve

d

TΔS=ΔHand  both  ΔHandΔS  are+ve

answer is C.

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Detailed Solution

ΔG=ΔHTΔS
ΔG=-ve for spontaneous reaction. 
When  ΔS=+ve,ΔH=+veandTΔS>ΔHΔG=ve
 

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