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Q.

A reaction proceeds by first order, 75% of this reaction was completed in 32 min. The time required for 50% completion is 

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a

16 min

b

8 min

c

20 min

d

24 min

answer is B.

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Detailed Solution

Given 75% reaction gets completed in 32 min

Thus, k=2.303tloga(ax)=2.30332log100(10075)

=2.30332log4=0.0433min1

Now we can use this value of k to get the value of time required for 50% completion of reaction

t=2.303kloga(ax)=2.3030.0433log10050

=2.3030.0433log2=16min 

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