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Q.

A reaction takes place in three steps. The rate constants are k1,k2 and k3. The overall rate constant k=k1k3k2. If (energy of activation) E1,E2 and E3 are 60, 30 and 10 kJ. The overall energy of activation is : 

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a

60

b

400

c

40

d

30

answer is A.

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Detailed Solution

K=AeEa/RTAeEa/RT=Ae-E1-E3+E2RTEa=E1+E3E2=60+1030=40kJ

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A reaction takes place in three steps. The rate constants are k1,k2 and k3. The overall rate constant k=k1k3k2. If (energy of activation) E1,E2 and E3 are 60, 30 and 10 kJ. The overall energy of activation is :