Q.

A reaction takes place in three steps with activation energy Ea1=180 kJ/mol, E¯a2=80 kJ/mol, Ea9=50 kJ/mol respectively overall rate contestant of the reaction is k=k1k2k32/3 the overall activation energy of reaction will be (Here k1,k2 and k3 a rate constant of first, second and third step respectively.) :

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a

140 kJ/mol

b

150 kJ/mol

c

43.44 kJ/mol

d

100 kJ/mol

answer is A.

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Detailed Solution

Overall activation energy of reaction,

Ea (overall) =23Ea1+Ea2Ea8

=23(180+8050)=140

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