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Q.

A reaction which is of first order w.r.t reactant A, has a rate constant is 6 min-1 If we start with A=0.5mol.L-1 ,when would A reach the value of 0.05mol.L-1

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a

0.384min

b

15min

c

20min

d

3.84min

answer is A.

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Detailed Solution

For 1st  order reaction

K=6min-1

At t=0 min,A0=0.5 mol.lit-1

At t=___ minA1=0.5 mol.lit-1

t=2.303KlogA0A

t=2.3036log0.50.05=2.3036log1010

=0.384 min

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