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Q.

(A) Reduction of a metal oxide is easier if the metal formed is in liquid state at the temperature of reduction.
(R) G° for the net reaction, reduction of metal oxide with the reductant, is more -ve when the metal formed is in molten state

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a

Both (A) and (R) are true and (R) is the correct explanation of (A)

b

Both (A) and (R) are true but (R) is not the correct explanation of (A)

c

(A) is true but (R) is false

d

Both (A) and (R) are false

answer is A.

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Detailed Solution

Reduction of a metal oxide is easier if the metal is formed in a liquid state at the temperatures of the reduction because the entropy is higher if the metal is in a liquid state.

Since the value of T△S increases and that of △H remains constant, therefore, the value of △r​G∘(△G=△H−T△S) becomes more −ve and hence the reduction becomes easier.

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