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Q.

A sample containing CaBr2 and NaI in mass ratio 29 was dissolved in water and treated with sufficient amount of aq. AgNO3 solution to form a mixed precipitate of AgI and AgBr. The weight of mixed precipitate was found to be 1786 gm.

[Na=23,Br=80,I=127,Ca=40]

Select the correct option.

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a

Number of moles of AgBr produced is 1

b

Mass of original sample was 900 gm

c

Mass of CaBr2 in the original sample was 400 gm

d

Moles of CaBr2 and N aI in the original sample was 1 and 6 respectively

answer is A.

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Detailed Solution

In the given reaction we have;

                       CaBr2,         NaI

Mass=              2W,        9W

Moles=           2W200,        9W1502W200×2×188+9W150×235=1786W=100

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