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Q.

A sample of an ideal gas has pressure p0, volume V0 and temperature T0. It is isothermally expanded to twice its original volume. It is then compressed at constant pressure to have the original volume V0. Finally, the gas is heated at constant volume to get the original temperature. The heat absorbed in the process is

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a

p0V0[ln 2 + 12]

b

poV0[ln 2 + 32]

c

p0V0[ln 2 + 2]

d

p0V0[ln 2-12]

answer is D.

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Detailed Solution

The process is cyclic so that the change in internal energy is zero. The heat supplied is, therefore, equal to the work done by the gas. The work done during ab is
W1 = nRT0ln 2V0V0 =nRT0ln 2 = p0V0ln 2

Also from the ideal gas equation,
pa Va = pbVb or pb = paVaVb = p0V02V0 = p02

In the step bc,the pressure remains constant. Hence the work done is, W2= p02(V0-2V0) = -p0V02
In the step ca,the volume remains constant and so the work done is zero. The net work done by the gas in the cyclic process is
W = W1 + W2 = p0V0[ln 2-12]

Hence, the heat supplied to the gas is p0V0[ln 2- 12]

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