Q.

A sample of chalk (CaCO3)   is contaminated with calcium sulphate  (CaSO4); 1 gm of the solid mixture is dissolved in 230mL of N/10 HCl.40mL of  N/10 NaOH solution is required to neutralise the excess of acid. The percentage of chalk in the mixture is. 

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a

90%

b

95%

c

5%

d

100%

answer is A.

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Detailed Solution

Meq of  CaCO3=(230×11040×110)=19    WCaCO3=19100×1002=0.95g
 
% Of  CaCO3  in mixture =  0.951×100=95%
 

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