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Q.

A sample of liquid X, is introduced into an evacuated chamber with a movable piston. The pressure is measured as a function of the volume of the container while the temperature is maintained at 50°C, and the graph below is obtained. Choose the correct group of statements. Question Image
I) At volumes below 60 mL, X is only present in the liquid phase.
II) At volumes above 60 mL, X is only present in the gaseous phase.
III) If the process were repeated at 60 °C, the point at which the pressure begins to decrease would shift to higher volume.
IV) If more ‘X’ were added to the container, the pressure at V = 20 mL would increase 

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a

II, IV only

b

II only

c

I, III, IV only

d

II, III, IV only

answer is C.

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Detailed Solution

At volumes above 60 mL, X is only present in the gaseous phase.

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