Q.

 A sample of  NaClO3 is converted by heat to NaCl with a loss of 0.16 g of oxygen. The residue is dissolved in water and precipitated as AgCl (molar mass of AgCl:143.5gmol1) obtained will be

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a

0.54 g

b

0.35 g

c

0.48 g

d

0.41 g 

answer is C.

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Detailed Solution

The reaction is NaClO3ΔNaCl+32O2

Amount of O2 released =0.16g32gmol1=0.005mol

Mass of AgCl precipitated =23×0.005mol(108+35.5)gmol1=0.48g

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