Q.

A sample of uranium is a mixture of three isotopes 92U234 , 92U235 and 92U238 present in the ratio 0.006%, 0.71% and 99.284% respectively. The half lives of then isotopes are 2.5×105 years, 7.1×108 years and 4.5×109 years respectively.  The contribution to activity (in %) of each isotope in the sample respectively

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a

51.41%, 2.13%, 46.46%

b

46.46%,2.13%,51.41%

c

51.41%, 46.46%, 2.13%

d

2.13%,51.41%, 46.46%

answer is A.

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Detailed Solution

Let m is the total mass of the uranium mixture. The masses of the isotopes  92U234 , 92U235 and 92U238  in the mixture are m1=0.006100m; m2=0.71100m, and m3=99.284100m.

If NA is the Avogadro number, then number of atoms of three isotopes are N1=m1NAM1;N2=m2NAM2, and N3=m3NAM3.

Activity of radioactive sample A = λN.

As λ =0.693t1/2, A=0.693t1/2N

 If t1,t2 and t3 be the half lives, then 

A1:A2:A3=N1t1:N2t2:N3t3 or  A1:A2:A3=m1M1t1:m2M2t2:m3M3t3

=0.0062342.5×105:0.712357.5×108:99.2842384.5×109=51.41%:2.13%:46.46%

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