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Q.

A saturated in  AgA  (Ksp=3×1014) and  AgB  (Ksp=1×1014) has conductivity of  375×1010  Scm1. Limiting molar conductivity of Ag+  and  A are 60  Scm2  mol1  and  80  Scm2  mol1 respectively. If the limiting molar conductivity of B  is Y (in  Scm2  mol1) . Find out the value of Y54 ?

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answer is 5.

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Detailed Solution

AgAAg+(S1+S2)+AS1[KSP=3×1011]

AgAAg+(S1+S2)+BS1[KSP=1014]

3×1014=S1(S1+S2)

1014=S2(S1+S2)

3=S1S2

S2=12×107  mole/l

S1=32×107  mole/l

K=375×1010

K=KAg++KA+KB

375×1010=λAg+(S1+S2)1000+λA(S1)1000+λB(S2)1000

375×107=60(2×107)+80(32×107)+λB×(12×107)

λB=270            Y=270;         Y54=5

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A saturated in  AgA  (Ksp=3×10−14) and  AgB  (Ksp=1×10−14) has conductivity of  375×10−10  Scm−1. Limiting molar conductivity of Ag+  and  A− are 60  Scm2  mol−1  and  80  Scm2  mol−1 respectively. If the limiting molar conductivity of B−  is Y (in  Scm2  mol−1) . Find out the value of Y54 ?