Q.

A saturated solution in AgA (Ksp=3×1014)andAgB(Ksp=1×1014) has conductivity of  375×1010Scm1. Limiting molar conductivity of Ag+andAare60Scm2mol1  and 80 Scm2mol1 respectively. If the limiting molar conductivity of B  is Y (inScm2mol1).  Find out the value of Y54? 

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answer is 5.

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Detailed Solution

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AgAAg+s1+s2+A s1Ksp=3×1011AgAAg+s1+s2+B-s2Ksp=1014
3×1014=S1S1+S21014=S2S1+S23=S1S2S2=12×107mole/S1=32×107mole/K=375×1010K=KAg++KA+KB375×1010λAg+S1+S21000+λAS11000+λBS21000 
375×107=602×107+8032×107+λB×12×107λB=270Y=270 ; Y54=5  

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