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Q.

A saturated solution of silver benzoate  C6H5CO2Ag has a pH of 8.63, Kα as benzoic acid is 6.5 x 10- 5 . Estimate the value of K of silver sp benzoate:

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a

1.287×10−2

b

1.399×10−2

c

None of these

d

1.49×10−3

answer is B.

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Detailed Solution

pH=12pKw+pKa+log⁡c⇒c=0.118ksp=c2=1.399×10−2

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