Q.

A saturated solution of silver bromide is made in  107M  AgNO3 solution 
Given:  Ksp   of   AgBr=3×1013
 λm(Ag+)=6×103Sm2mol1         λm(NO3)=7×103Sm2mol1         λm(Br)=8×103Sm2mol1
For water,  k=7.5×106Sm1
The conductivity of solution is  x×107Sm1. The value of  x/10 is…..

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answer is 15.7.

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Detailed Solution

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Let solubility of  AgBr(s) in AgNO3 solution be s(M)

AgBr(s) Ag+    +     Br

(s+107)s        (s+107)=3×1013     or  s2+10-7s30×1014=0         or  s2+6×10-7s5×107(s2+6×10-7)=0          s(s+6×10-7)5×107(s+6×10-7)=0         or  s(s-5×10-7)(s+6×10-7)=0         s=5×10-7(M)

πm(AgNO3)=λm(Ag+)+λm(NO3)=13×103sm2mol1           πm(AgBr)=λm(Ag+)+λm(Br)=14×103sm2mol1            k(AgBr)=[πm(AgBr)]C=70×107sm1        ksolution=k(AgNO3)+k(AgBr)+k(H2O)=(13×107+70×107+75×107) =158×107sm1)x10=15.8

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