Q.

A saturated solution of sparingly soluble base Fe(OH)3 is found to have a specific conductance of 50×104ohm1m1.
Given λeqFeCl3=10×103Sm2eq1
λeqNaCl=16×103Sm2eq1
λeqNaOH=23×103Sm2eq1,specific conductance of water is negligible, Then

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a

solubility of Fe(OH)3 in a solution of pH = 13 is 2.2×107

b

Ksp of Fe(OH)3 is 2.7×1015

c

Ksp of Fe(OH)3 is 2.2×1010

d

solubility of Fe(OH)3 in a solution of pH = 13 is 2.7×1012

answer is A, C.

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Detailed Solution

λ Fe(OH)3=λFeCl3+λNaOHλNaCl, μFe(OH)3=3λFe(OH)3 μFe(OH)3=k×1000/S Ksp=2754 In the presence of OHions S=Ksp/[OH]3

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