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Q.

A schematic plot of lnKc versus inverse of temperature for reaction is shown below
Which of the following statement(s) is/are correct regarding the reaction?

xAyB    KC=[B]y[A]x

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a

Sign of ΔrH0 is positive 

b

Sign of ΔrS0 is negative 

c

ΔrG0 is negative at all temperature

d

At equilibrium, rate of consumption of A is equal to rate of formation of B

answer is A.

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Detailed Solution

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lnKc=ΔH0RT+TΔS0RT      lnKc=ΔH0R(1T)+ΔS0R       y = m x + c

slope of curve is negative it means ΔH0 is positive and value of Kc is less than unity hence, reaction is non-spontaneous at standard condition

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