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Q.

 (A) : [SiF6]2 is formed but [SiCl6]2 is not

(R) : Electronegativity (EN) of F is higher than EN of  Cl

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a

Both A and R are correct and R is the correct explanation of A

b

Both A and R are correct and R is not the correct explanation of A

c

A is correct but R is not correct

d

A is not correct but R is correct

answer is B.

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Detailed Solution

Six large chloride ions cannot be accommodated around Si+4 due to limitation of its size. 

A is correct.

F is more electronegative than chlorine, in fact it is most electronegative element of the periodic table but its electron affinity, the tendency to accommodate electrons, is less than the Cl due to non availability of d-electrons.

R is incorrect.

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