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Q.
(A) SN2 reactions are exothermic
(R) SN2 reactions are thermochemically favored by stronger nucleophiles
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a
Both (A) and (R) are correct and (R) isthe correct explanation of (A)
b
(A) is True but (R) is False
c
Both (A) and (R) are false
d
Both (A) and (R) are correct but (R) is not the correct explanation of (A)
answer is A.
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Detailed Solution
SN2 reactions (bimolecular nucleophilic substitution reactions) occur in a single step, where the nucleophile attacks the substrate and simultaneously displaces the leaving group. These reactions are often exothermic because the products (typically a stronger bond between the nucleophile and the substrate) are more stable than the reactants. The reaction is thermochemically favored by stronger nucleophiles, which have higher electron density and are more reactive in attacking the substrate.
Explanation:
(A) SN2 reactions are exothermic: This statement is true because the formation of a stronger bond between the nucleophile and the substrate releases energy, making the reaction exothermic in most cases.
(R) SN2 reactions are thermochemically favored by stronger nucleophiles: This statement is also true because stronger nucleophiles are more reactive and result in faster and more efficient substitution reactions. However, the exothermic nature of SN2 reactions is due to bond formation and not solely because of the nucleophile's strength.
Since both (A) and (R) are correct, but (R) does not directly explain why SN2 reactions are exothermic, the correct option is:
b) Both (A) and (R) are correct, but (R) is not the correct explanation of (A).