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Q.

A solid crystallises in a hexagonal structures as shown in the figure, if the density of solid is 23gm/cm3.How many molecules are present in the given unit cell.

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Take Avogadro’s number =6×1023, Atomic mass of solid =450

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a

b

6

c

18

d

4

answer is A.

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Detailed Solution

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a3=volume=10A0×10A0×sin600×15A0

Z=d×a3.NoM=23×7503×1024×6×1023450

Z=6

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