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Q.

A solid X held in a test tube received acetic acid addition. A colourless and odourless gas has evolved. The gas was passed through lime water which turned the water milky. It was concluded that:

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a

X is sodium hydroxide, and CO2  is the gas evolved.

b

X is sodium bicarbonate and the gas evolved is CO2

c

The gas evolved is  CO2 from solid X, which is sodium acetate.

d

Sodium chloride is the solid X, and CO2 is the gas evolved.  

answer is B.

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Detailed Solution

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When acetic acid reacted with X a colourless gas was given out. This gas turns lime water milky which suggests that it has carbon dioxide. Hence the gas released is carbon dioxide. So X should have been carbonate or bicarbonate

It was concluded that solid X is sodium bicarbonate and the gas evolved is CO2 .

And the reaction occurs as follows:
CH3COOH(aq)+NaHCO3(aq)Na(CH3COO)(aq)+H2O(aq)+CO2(g)

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A solid X held in a test tube received acetic acid addition. A colourless and odourless gas has evolved. The gas was passed through lime water which turned the water milky. It was concluded that: