Q.

A solution containing 1.8 g of a compound ( empirical

formula CH2O ) in 40g of water is observed to freeze at 

-0.465° C. The molecular formula of the compound is

Kf of water =1.86kgKmol1

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a

C4H8O4

b

C6H12O6

c

C3H6O3

d

C2H4O2

answer is D.

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Detailed Solution

ΔTf=Kf×m0.465=1.86×1.8M×100040M=180

Molecular formula=( empirical formula )n

n= Molecular mass  Empirical formula mass =18030=6 Molecular formula =CH2O6=C6H12O6.

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A solution containing 1.8 g of a compound ( empiricalformula CH2O ) in 40g of water is observed to freeze at -0.465° C. The molecular formula of the compound isKf of water =1.86kgKmol−1