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Q.

A solution containing 3.3g of a substance in 125g of benzene (b.pt. = 80oC) boils at 80.66OC. If Kb for benzene is 3.28 K kg mol–1 the molecular mass of the substance will be: 

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a

130.20

b

131.20

c

132.20

d

129.20

answer is D.

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Detailed Solution

Tb=Kbm Tb=0.66 0.66=Kb×WsMs×1mass of solvent(kg) 0.66=3.283.3M×10.125 M=131.20g

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