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Q.

A solution containing 62 g ethylene glycol in 250g water is cooled to 100C . If Kf  for water is 1.86 K kg mol1 , the amount of water (in g ) separated as ice is 

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a

16

b

48

c

64

d

32

answer is A.

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Detailed Solution

ΔTf=Kf×W2M2×1000W1

Where,  W1= mass of solvent H2O 
W2=  mass of solute (ethylene glycol)
 M2= molar mass of solute
 W1=Kf×W2×1000ΔTf×M2=1.86×62×100010×62=186g
 Amount of water separated as ice =  
250186g=64

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