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Q.

A solution containing 8.6 g urea in one litre was found to be isotonic with a 5% (wt./vol.) solution of an organic non-volatile solute. The molecular weight of latter is : 

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a

861.2

b

3489

c

34.89

d

348.9

answer is A.

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Detailed Solution

For two non-electrolytic solutions if isotonic C1=C2

∴ 8.660×1=5×1000m×100  ∴ m=348.9

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