Q.

A solution containing 2.5×10-3 kg of a solute dissolved in 75×10-3 kg of water boils at 373.535 K . The molar mass of the solute is ______ g mol-1. [nearest integer] (Given: KbH2O=0.52 K Kg mol-1, boiling point of water =373.15 K )

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answer is 45.

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Detailed Solution

The molar mass of the solute is 45 g mol-1.

w=2.5 g , Kb=0.52wsolvent =75 g,M= Mol. Wt. of solute TB'=373.535 K 

TBo=373.15 K
ΔTB=Kbm=0.385 
0.385=0.52×2.5M×100075
M=45 g mol-1

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A solution containing 2.5×10-3 kg of a solute dissolved in 75×10-3 kg of water boils at 373.535 K . The molar mass of the solute is ______ g mol-1. [nearest integer] (Given: KbH2O=0.52 K Kg mol-1, boiling point of water =373.15 K )