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Q.

A solution containing Mn+2 is reacted with ‘v’ ml of 0.2 M MnO4 in aqueous medium such

            that the species comproportonate completely into Mn3+. The resultant solution consumed

            50ml 0.1M Hypo iodometry. What can be concluded (Mn3++IMn2++I2)

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a

The Eq. wt of  Mn+3 is not same in both reactions

b

The first solution contains 4 millimoles of Mn+3

c

The no. of equivalents of Mn+3 is same in comproportionation and iodometry.

d

The value of ‘v’ is 5    

answer is A.

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Detailed Solution

Mn2++MnO4Mn3+

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A solution containing Mn+2 is reacted with ‘v’ ml of 0.2 M MnO4− in aqueous medium such            that the species comproportonate completely into Mn3+. The resultant solution consumed            50ml 0.1M Hypo iodometry. What can be concluded (Mn3+ + I− → Mn2+  + I2)