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Q.

A solution contains 0.1 M NaCl, 0.01 M NaBr and 0.001 M Nal. Solid AgNO3 is gradually added to the solution and its addition does not change the volume of solution :

 Ksp(AgCl) = 10-10, KSP(AgBr) = 10-13, KSP(Agl)​ = 10-17   . Choose the correct statement.

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a

When the precipitation of AgCl just starts, [I] in the solution is  108M

b

If sufficient Nal is added to a saturated solution of AgCl, precipitate of Agl is obtained 

c

Agl precipitates first 

d

The maximum  [Ag+] which can be maintained in the solution so that only Agl is precipitated

is  1011M

answer is A, B, C, D.

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Concept of selective precipitation

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A solution contains 0.1 M NaCl, 0.01 M NaBr and 0.001 M Nal. Solid AgNO3 is gradually added to the solution and its addition does not change the volume of solution : Ksp(AgCl) = 10-10, KSP(AgBr) = 10-13, KSP(Agl)​ = 10-17   . Choose the correct statement.