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Q.

A solution contains non-volatile solute of molecular mass M_P . Which of the fallowing can be used to calculate molecular mass of the solute in terms of osmotic pressure (m = Mass of solute, V = Volume of solution and $π$ = Osmotic pressure)

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a

$M p = (\frac{m}{V}) π R T$

b

$M p = (\frac{m}{V}) \frac{R T}{π}$

c

$M p = (\frac{m}{V}) \frac{π}{R T}$

d

$M p = (\frac{m}{π}) V R T$

answer is B.

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Detailed Solution

$π = \frac{n}{V} R T \Rightarrow M_{P} = (\frac{m}{V}) \frac{R T}{π}$

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