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Q.

A solution contains OH- equal to 10-6M .Which of the following hydroxides will get precipitated when this solution is added in an equal volume to a solution containing 0.1 M of metal ions?

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a

AgOH(KSp=5'10-3)

b

Cd(OH)2(KSp=8'10-6)

c

Mg(OH)2(KSp=3'10-11)

d

Fe(OH)2(KSp=8'10-16)

answer is D.

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Detailed Solution

AgOHAg+OH-

KSp=S2=5×10-3S=5×10-3=6.7×10-2

Cd(OH)2Cd+2+2OH-

     S              2S

KSp=4S2S=KSp43=2×10-63=2×10-23

(iii) Mg(OH)2S=7.5×10-43

(iv) Fe(OH)2Fe++2OH-

S          2S

KSp=4S2S=KSp43

=8×10-643=0.2×10-53

Fe(OH)2

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