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Q.

A solution is prepared by mixing ethanol and water. The mole fraction of ethanol in the mixture is 0.9. Given vapour pressure of pure water and vapour pressure of pure ethanol are 32.8 mm Hg and 40 mm Hg respectively. The vapour pressure of solution M is

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a

29.5 mm Hg

b

39.3 mm Hg

c

36.0 mm Hg

d

28.8 mm Hg

answer is A.

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Detailed Solution

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P = total vapour pressure.

 P=pA°XA+pB°XB    =40×0.9+32.8×0.1since X=XA+XB    =39.28 mm Hg39.3 mm Hg    

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