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Q.

A solution of ( + )-2-chloro-2-phenylethane in toluene racemises slowly in the presence of small amount of SbCl5, due to the formation of

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a

carbanion

b

carbene

c

free-radical

d

carbocation

answer is D.

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Detailed Solution

A solution of (−)−1-chloro-1-phenylethane in toluene racemises slowly in the presence of a small amount of SbCl5, due to the formation of carbocation. Carbocation has planar geomety. Hence, the nucleophile can attack from either side. 

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