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Q.

A solution of (+)-2-chloro-2-Phenyl Ethane in toluene racemises slowly in the presence of small amount of SbCl5, due to the formation of

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a

Carbocation

b

Carbene

c

free- radical

d

Carbanion

answer is D.

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Detailed Solution

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Explanation:

The racemization of (+)-2-chloro-2-phenyl ethane (which is a chiral compound) occurs due to the formation of a planar carbocation intermediate. When a base (like sodium hydroxide, NaOH) is present, it can abstract a proton from the β-carbon of the molecule, resulting in the formation of a carbocation at the chiral center. This carbocation is planar and can be attacked from either side, leading to the formation of both the R and S enantiomers. This process is known as racemization, as it converts the optically active (+)-enantiomer into a racemic mixture (an equal mixture of both R and S enantiomers).

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