Q.

A solution of 0.1 M  CH3COOH is placed between parallel electrodes of cross-section
area  4cm2, separated by 2 cm. For this solution, resistance measured is  100Ω. Calculate elevation in boiling point of the 0.1 M CH3COOH  solution, using following  information Kb=0.5K  kg/mol;Λm(H+)=300Scm2mole1;

Λm(CH3COO)=100S  cm2mole1

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answer is 0.06.

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Detailed Solution

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lA=24;R=ρ.12orρ=200Ω         κ=1200Ω1cm1        Λ=1200×10000.1=50Λ0=300+100=400α=ΛΛ0=50400=18ΛTb=i×Kb×m=(1+18)×0.5×0.0.05625

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