Q.

A solution of 0.1M KMnO4 is used for the reaction S2O32+2MnO4+H2OMnO2+SO42+OHThe volume of KMnO4 required to react 0.158gm of Na2S2O3 is (MW = 158)

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a

3.33 ml

b

6.66 ml

c

26.67 ml

d

13.33 ml

answer is D.

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Detailed Solution

No. of milli equivalents of KMnO4 = No. of
milli equivalents of thiosulphate ions
V×0.1×3=0.1581588×1000 ;V=803=26.67ml

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