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Q.

A solution of 0.450 g of urea (mol. wt. 60) in 22.5 g of water showed 0.170oC of elevation in boiling point. Calculate the molal elevation constant of water. 

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a

0.17oC

b

0.45oC

c

0.51oC

d

0.30oC

answer is C.

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Detailed Solution

Weight of solute, w = 0.450 g

Weight of solvent, W = 22.5 g

Molecular weight of solute, m = 60

Molal elevation constant Kb=?

Boiling point elevation, ΔTb=0.170oC

Substituting these values in the equation Kb=m×W×ΔTb1000×w

                                                                           =60×22.5×0.1701000×0.450=0.51oC

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