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Q.

A solution of 1.73 g of 'A' ( non-volatile and non-electrolyte ) in 100 cc of water is found to be isotonic with a 3.42% (wt. /vol.) solution of sucrose (C12H22O11) at same temperature. Molecular weight of ‘A’ is______g/mole. (C12H22O11=342)

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answer is 173.

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Detailed Solution

We know that the isotonic solutions have the same molar concentration (i.e.,moles/lit).
 Let the molecular weight of A be M
Molar conc. Of A (moles/ litre) =1.73M×1000100=17.3M
Molar conc.of sucrose=3.42342×1000100=0.1
17.3M=0.1;M=173

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A solution of 1.73 g of 'A' ( non-volatile and non-electrolyte ) in 100 cc of water is found to be isotonic with a 3.42% (wt. /vol.) solution of sucrose (C12H22O11) at same temperature. Molecular weight of ‘A’ is______g/mole. (C12H22O11=342)