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Q.

A solution of two liquids boils at a temperature more than the boiling point of either of them. What type of deviation will be shown by the solution formed in terms of Raoult's law ?

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a

First positive then negative

b

Negative deviation

c

First negative then positive

d

Positive deviation

answer is A.

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Detailed Solution

Since the Boiling point of the solution is more than the Boiling point of the individual components in the solution, it indicates that the vapour pressure exerted by the solution is less than the expected, as boiling starts when vapour pressure equals the atmospheric pressure. Hence, the solution shows a negative deviation from the Raoult's law.

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A solution of two liquids boils at a temperature more than the boiling point of either of them. What type of deviation will be shown by the solution formed in terms of Raoult's law ?