Q.

A solution prepared by dissolving a 2.50 g sample of an unknown compound dissolved in 34.0 g of benzene, C6H6, boils 1.38° C higher than pure benzene. Which expression gives the molar mass of the unknown compound?

CompoundKb
C6H62.53C.m1

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a

2.50×103×2.531.38×2.53

b

1.38×34.02.53×2.50

c

2.53×2.501.38

d

2.50×103×2.531.38×134

answer is C.

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Detailed Solution

Boling temperature change,

ΔTb=Kb×m

1.38=2.53×2.50M34×1000

M=2.50×103×2.531.38×134

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