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Q.

A sparingly soluble salt of solubility ‘S’ has the formula Tl6Al(PO4)3 and has a solubility product of kS2y where k is a constant. The value of ‘y’ is [Thallium (Tl) is univalent ion and Aluminium (Al) is trivalent ion

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answer is 5.

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Detailed Solution

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  BaF2(s)Ba2+(aq)+2F(aq)
Let ‘S’ be the solubility of BaF2, but Ba2+ reacts with C2O42 present in this solution &  almost completely convert into BaC2O4
 Ba2++C2O42BaC2O4(s)
Let y mole per it of Ba2+ is left after reaching equilibrium
So,    Ba2++C2O42 BaC2O6(s)keq=101
  y0.1s
So, we get the following two questions,
 y(0.1s)=102&y(2s)2=104=(Khp)BaF2
Solving there two equations,
We get,  S=0.096M
So,  (C2O42)=0.10.096=4×103M
 [F]=2s=2×0.0960.192M
 [B2+]=y=2.7×105M

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