Q.

(a) State Raoult’s law. How is it formulated for solutions of non-volatile solutes?

(b) State Henry’s law and mention two of its important applications. 

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Detailed Solution

(a) Raoult’s Law,

For a solution of volatile liquids,

The partial vapour pressure of each component in the solution α mole fraction.

Psolution = Xsolvent . P0solvent

Where,

Psolution = Vapour pressure of the solution.

X solvent = Mole fraction of the solvent.

P0solvent = Vapour pressure of the pure solvent

(b) Henry’s law:

The partial pressure of the gas in vapour phase  α  mole fraction of the gas in the solution.

Important applications of Henry’s law:

  1. To increase the solubility of CO2 in soft drinks.
  2. Oxygen is diluted with helium gas to avoid bends in scuba drivers.
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